Beilstein J. Org. Chem.2016,12, 1372–1379, doi:10.3762/bjoc.12.131
polymerization. All complexes investigated show very high catalytic activity and the additional side arm minimizes chain-transfer reactions, leading to increase of molecular weights of the resulting polymers.
Keywords: chromiumsingle-sitecatalysts; olefin polymerization; ultra-high molecular weight
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Graphical Abstract
Scheme 1:
Influencing catalyst stability, olefin coordination and chain-transfer reactions by hemilabile dono...